Knorn, Matthias and Lutsker, Eugen and Reiser, Oliver (2020) Isonitriles as supporting and non-innocent ligands in metal catalysis. CHEMICAL SOCIETY REVIEWS, 49 (21). pp. 7730-7752. ISSN 0306-0012, 1460-4744
Full text not available from this repository. (Request a copy)Abstract
Isonitriles, being competent sigma-donors, show a strong aptitude to form transition-state metal complexes. Nevertheless, until the end of the last century, few metal-isonitrile catalyzed processes were known. Only more recently, scientists recognized the considerable potential of isonitriles as ligands in metal catalysis utilizing both commercially available but also specially designed representatives of this compound class. Isonitrile ligands, which can be both innocent or non-innocent constituents in metal complexes, contributed to the discovery of new catalytic processes and thereby to one of the fastest growing areas of organic chemistry. This review focuses on the special properties and attributes metal-isonitrile complexes offer towards their application in catalysis.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | INTRAMOLECULAR BIS-SILYLATION; TERT-ALKYL ISOCYANIDE; SYNTHETIC REACTIONS; STEREOSELECTIVE-SYNTHESIS; COMPLEX CATALYSTS; MULTICOMPONENT REACTIONS; CYCLIC-COMPOUNDS; STRAIGHTFORWARD APPROACH; TRANSFER HYDROGENATION; PHOTOREDOX CATALYSIS; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser |
| Depositing User: | Petra Gürster |
| Date Deposited: | 21 Apr 2021 06:36 |
| Last Modified: | 21 Apr 2021 06:36 |
| URI: | https://pred.uni-regensburg.de/id/eprint/43400 |
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