Roesch, Andreas and Herzog, Christoph M. and Schreiner, Simon H. F. and Goerls, Helmar and Kretschmer, Robert (2020) Ditopic bis(N,N ',N '-substituted 1,2-ethanediamine) ligands: synthesis and coordination chemistry. DALTON TRANSACTIONS, 49 (39). pp. 13818-13828. ISSN 1477-9226, 1477-9234
Full text not available from this repository. (Request a copy)Abstract
The synthesis of two different types of bis(N,N',N'-substituted 1,2-ethanediamine)s, bridged either through the secondary (type 1) or tertiary (type 2) amine groups is reported. Selected protio-ligands have been applied in subsequent metallation reactions using aluminium, magnesium, tin, and zinc sources allowing to isolate five mononuclear and eight dinuclear complexes. All complexes have been fully characterized and their solid-state structures have been studied by means of single-crystal X-ray diffraction analysis. Nine of the 13 complexes carry reactive alkyl, amide or hydride groups, which indicates their potential as catalysts or supports for (transition) metals.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | BRIDGED BIS(GUANIDINATE) LIGAND; ANSA BIS(AMIDINATE) LIGAND; MAIN-GROUP ELEMENTS; STRUCTURAL-CHARACTERIZATION; LINKED BIS(AMIDINATE); HETEROMETALLIC COMPLEXES; LACTIDE POLYMERIZATION; BINUCLEATING LIGANDS; CATALYTIC-ACTIVITY; CRYSTAL-STRUCTURES; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 08 Mar 2021 14:09 |
| Last Modified: | 08 Mar 2021 14:09 |
| URI: | https://pred.uni-regensburg.de/id/eprint/43539 |
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