Vogler, Arnd (2015) MLCT interaction in [Rh(II)(2)(CO3)(4)](4-) (x L). INORGANIC CHEMISTRY COMMUNICATIONS, 62. pp. 5-7. ISSN 1387-7003, 1879-0259
Full text not available from this repository.Abstract
Complexes of the type [Rh-2(II)(CO3)(4)(H2O)(L)](n-) with L = N-methylpyrazinium(+) and 1-heptyl-4-(4-pyridinyl)pyridinium(+) cations display intense long-wavelength (Rh(II) to L) MLCT absorptions. With L = H2O, MLCT absorptions are not identified, but the photoreactivity of the complex in aqueous solution supports the assumption that (Rh(II) to CO32-) MLCT excited states are accessible. Upon irradiation with white light, Rh(II) is photooxidized while carbonate is reduced to CO. The efficiency of this photolysis is very low. However, the occurrence of this photoredox reaction is, nevertheless, of general interest with regard to the photochemical reduction of CO2. (C) 2015 Elsevier B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | COMPLEXES; DIRHODIUM(II); BOND; Photochemistry; Rhodium(II); Carbonate; Photoreduction of CO2; MLCT excitation |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 02 May 2019 11:29 |
| Last Modified: | 02 May 2019 11:29 |
| URI: | https://pred.uni-regensburg.de/id/eprint/4368 |
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