Yadav, Ravi and Goswami, Bhupendra and Simler, Thomas and Schoo, Christoph and Reichl, Stephan and Scheer, Manfred and Roesky, Peter W. (2020) A bis(germylene) functionalized metal-coordinated polyphosphide and its isomerization. CHEMICAL COMMUNICATIONS, 56 (70). pp. 10207-10210. ISSN 1359-7345, 1364-548X
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Pentaphosphaferrocene, [Cp*Fe(eta(5)-P-5)] (Cp* = eta(5)-C5Me5), was used as a polyphosphorus source to obtain germylene-polyphosphide complexes. A stepwise reactivity was observed between the di-germylene, [LGe-GeL] (L = {PhC((NBu)-Bu-t)(2)}), and [Cp*Fe(eta(5)-P-5)]. Firstly, reductive homolytic cleavage of the Ge-Ge single bond in [LGe-GeL] led to [(LGe)(2){(mu,eta(4)-P-5)FeCp*}]. This complex showed an unprecedented isomerization.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | P-4 ACTIVATION; PHOSPHORUS; COMPLEXES; REACTIVITY; SILYLENE; ELEMENTS; BOND; GE; PENTAPHOSPHAFERROCENE; CLUSTER; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 11 Mar 2021 12:50 |
| Last Modified: | 11 Mar 2021 12:50 |
| URI: | https://pred.uni-regensburg.de/id/eprint/43814 |
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