Chernysheva, A. M. and Virovets, A. V. and Peresypkina, E. V. and Timoshkin, A. Yu. (2020) Structure of the Product of 1,3,5,7-Tetra-tert-butyloctahydro-1H,4aH-imidazo[4 ',5 ':5,6]dioxino[2,3-d]imidazole Cocrystallization with 1,3-Di-tert-butylimidazol-2-one and 1,3-Di-tert-butylimidazolin-2-ylidene. RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 90 (9). pp. 1625-1629. ISSN 1070-3632, 1608-3350
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Structure of the product of imidazolidine (1,3,5,7-tetra-tert-butyloctahydro-1H,4aH-imidazo[4MODIFIER LETTER PRIME,5MODIFIER LETTER PRIME:5,6]dioxino[2,3-d]imidazole) ether cocrytallization with 1,3-di-tert-butylimidazol-2-one and 1,3-di-tert-butylimidazolin-2-ylidene was established by single crystal X-ray diffraction. The co-crystal is the product of the oxidation-hydrolysis of the 1,3-di-tert-butylimidazolin-2-ylidene complex with AlH3.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | N-HETEROCYCLIC CARBENES; DERIVATIVES; REACTIVITY; OXIDATION; NHC; imidazolidine; imidazol-2-one; imidazolin-2-ylidene; N-heterocyclic carbene; reactivity |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 12 Mar 2021 09:59 |
| Last Modified: | 12 Mar 2021 09:59 |
| URI: | https://pred.uni-regensburg.de/id/eprint/43897 |
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