Karan, Sujoy and Geng, Yan and Decurtins, Silvio and Liu, Shi-Xia and Repp, Jascha (2020) Gold-linked strings of donor-acceptor dyads: on-surface formation and mutual orientation. CHEMICAL COMMUNICATIONS, 56 (57). pp. 7901-7904. ISSN 1359-7345, 1364-548X
Full text not available from this repository. (Request a copy)Abstract
Strings of gold-organic oligomers of polar units have been formed by on-surface synthesis and investigated with non-contact atomic force microscopy. The mutual alignment of dipoles within the strings is analyzed. While an alternating head-to-tail alignment might be expected from dipolar interactions, a more complicated alignment order is observed. The data suggests that coordination bonding to additional gold adatoms leads to stabilization of parallel pairs of molecules, suppressing a head-to-tail alignment order.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | TETRATHIAFULVALENE-BENZOTHIADIAZOLE DYAD; ATOMIC-FORCE MICROSCOPY; MOLECULE; REACTIVITY; AU(111); CHARGE; |
| Subjects: | 500 Science > 530 Physics |
| Divisions: | Physics > Institute of Experimental and Applied Physics Physics > Institute of Experimental and Applied Physics > Chair Professor Giessibl > Group Jascha Repp |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 18 Mar 2021 07:44 |
| Last Modified: | 18 Mar 2021 07:44 |
| URI: | https://pred.uni-regensburg.de/id/eprint/44185 |
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