Barham, Joshua P. and Koenig, Burkhard (2020) Synthetic Photoelectrochemistry. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 59 (29). pp. 11732-11747. ISSN 1433-7851, 1521-3773
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Photoredox catalysis (PRC) and synthetic organic electrochemistry (SOE) are often considered competing technologies in organic synthesis. Their fusion has been largely overlooked. We review state-of-the-art synthetic organic photoelectrochemistry, grouping examples into three categories: 1) electrochemically mediated photoredox catalysis (e-PRC), 2) decoupled photoelectrochemistry (dPEC), and 3) interfacial photoelectrochemistry (iPEC). Such synergies prove beneficial not only for synthetic "greenness" and chemical selectivity, but also in the accumulation of energy for accessing super-oxidizing or -reducing single electron transfer (SET) agents. Opportunities and challenges in this emerging and exciting field are discussed.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | LIGHT PHOTOREDOX CATALYSIS; ACCURATE OXIDATION POTENTIALS; ELECTRON-TRANSFER REACTIONS; EXCITED-STATE DYNAMICS; CARBON BOND FORMATION; C-H AMINATION; RADICAL IONS; 2,3-DICHLORO-5,6-DICYANO-1,4-BENZOQUINONE DDQ; 9-MESITYL-10-METHYLACRIDINIUM ION; ELECTROCHEMICAL REDUCTION; electrochemistry; mediators; photoelectrochemistry; photoelectrodes; photoredox catalysis |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König |
| Depositing User: | Petra Gürster |
| Date Deposited: | 14 Apr 2021 06:56 |
| Last Modified: | 14 Apr 2021 06:56 |
| URI: | https://pred.uni-regensburg.de/id/eprint/44216 |
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