An entirely solvent-free photooxygenation of olefins under continuous flow conditions

Bayer, Patrick and Jacobi von Wangelin, Axel (2020) An entirely solvent-free photooxygenation of olefins under continuous flow conditions. GREEN CHEMISTRY, 22 (8). pp. 2359-2364. ISSN 1463-9262, 1463-9270

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Abstract

Photooxygenations of alkenes with singlet oxygen are a versatile, atom-economical transformation. The choice of solvents is key to the success of this oxyfunctionalization with direct impact on the solubility of substrates, the lifetime of the reactive oxygen species, and the up-scaling of the process. We report an entirely solvent-free continuous-flow photooxygenation that operates at very high substrate/sensitizer ratios and enables high space-time yields.

Item Type: Article
Uncontrolled Keywords: SINGLET OXYGEN; ENE REACTION;
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie
Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Axel Jacobi von Wangelin
Depositing User: Dr. Gernot Deinzer
Date Deposited: 26 Mar 2021 09:44
Last Modified: 26 Mar 2021 09:44
URI: https://pred.uni-regensburg.de/id/eprint/44723

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