Heinl, Sebastian and Peresypkina, Eugenia and Sutter, Joerg and Scheer, Manfred (2015) Giant Spherical Cluster with I-C-140 Fullerene Topology. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 54 (45). pp. 13431-13435. ISSN 1433-7851, 1521-3773
Full text not available from this repository. (Request a copy)Abstract
We report on an effective cluster expansion of CuBr-linked aggregates by the increase of the steric bulk of the Cp-R ligand in the pentatopic molecules [(CpFe)-Fe-R((5)-P-5)]. Using [(CpFe)-Fe-BIG((5)-P-5)] (Cp-BIG=C-5(4-nBuC(6)H(4))(5)), the novel multishell aggregate [{(CpFe)-Fe-BIG((5:2:1:1:1:1:1)-P-5)}(12)(CuBr)(92)] is obtained. It shows topological analogy to the theoretically predicted I-C-140 fullerene molecule. The spherical cluster was comprehensively characterized by various methods in solution and in the solid state.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | LOW-ENERGY ISOMERS; METAL CENTERS; KEPLERATE; OXIDE; PD-145(CO)(X)(PET3)(30); STABILIZATION; EXTRACTION; MOLECULES; LIGAND; UNITS; C-140 fullerene; Cp-BIG; giant clusters; pentaphosphaferrocene; supramolecular chemistry |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 06 May 2019 08:18 |
| Last Modified: | 06 May 2019 08:18 |
| URI: | https://pred.uni-regensburg.de/id/eprint/4481 |
Actions (login required)
 |
View Item |
