Biopolymers in sorbent-based microextraction methods

Pacheco-Fernandez, Idaira and Allgaier-Diaz, Diego W. and Mastellone, Giulia and Cagliero, Cecilia and Diaz Diaz, David and Pino, Veronica (2020) Biopolymers in sorbent-based microextraction methods. TRAC-TRENDS IN ANALYTICAL CHEMISTRY, 125: 115839. ISSN 0165-9936, 1879-3142

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Abstract

Since the introduction of the Green Analytical Chemistry guidelines, there has been an increasing concern on the sustainability of sample preparation approaches, particularly if considering they constitute the most time-consuming step of the analytical method and the main source of laboratory wastes. Among the alternatives explored, it is important to highlight the miniaturization of the extraction methods, which has been accompanied by the seek of greener solvents and sorbents. Biopolymers emerge as potential candidates to be used as sorbents in microextraction schemes given their biodegradability, versatility, and easily functionalization. This review offers an overview on biopolymers (chitosan, cellulose, alginate, and agarose) in sorbent-based microextraction approaches, paying attention to the preparation of the sorbent and the format in which biopolymers are incorporated into the sorbent/device, thus implying a specific microextraction approach, their role in the resulting sorbent material, and the reported analytical applications, covering environmental, food, and bioclinical analysis. (c) 2020 Elsevier B.V. All rights reserved.

Item Type: Article
Uncontrolled Keywords: SOLID-PHASE-EXTRACTION; PERFORMANCE LIQUID-CHROMATOGRAPHY; POLYCYCLIC AROMATIC-HYDROCARBONS; THIN-FILM MICROEXTRACTION; MAGNETIC CELLULOSE NANOPARTICLES; POLYBROMINATED DIPHENYL ETHERS; MOLECULARLY IMPRINTED POLYMERS; MULTIWALLED CARBON NANOTUBES; MIXED MATRIX MEMBRANE; SORPTIVE EXTRACTION; Biopolymer; Microextraction; Chitosan; Cellulose; Alginate; Agarose; Solid-phase extraction
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. David Díaz Díaz
Depositing User: Petra Gürster
Date Deposited: 09 Apr 2021 07:53
Last Modified: 09 Apr 2021 07:53
URI: https://pred.uni-regensburg.de/id/eprint/44812

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