A Retrosynthetic Approach for Photocatalysis

Petzold, Daniel and Giedyk, Maciej and Chatterjee, Anamitra and Koenig, Burkhard (2020) A Retrosynthetic Approach for Photocatalysis. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2020 (10). pp. 1193-1244. ISSN 1434-193X, 1099-0690

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Abstract

Visible-light-mediated chemical reactions have become very popular within the last 15 years. Many excellent reviews have summarized reaction principles and recent results in photochemistry and photocatalysis. However, despite their popularity photochemistry and photoredox catalysis are not regular parts of the bachelor and master curriculum of chemistry education. As a consequence, most chemists will use in synthesis planning classic retrosynthetic disconnections and only rarely consider photocatalytic steps. The aim of this article is to be a useful tool for synthetic chemists, that are interested in the synthetic aspects of photocatalysis and looking for a specific retrosynthetic disconnection. Not only are informative schemes provided but also are the availability of the catalysts and reagents as well as the functional group tolerance of the respective method briefly discussed.

Item Type: Article
Uncontrolled Keywords: VISIBLE-LIGHT PHOTOREDOX; C-H ARYLATION; CROSS-COUPLING REACTIONS; TRANSFER RADICAL-ADDITION; THIOL-ENE REACTIONS; COPPER-CATALYZED ALKYLATION; ALIPHATIC CARBOXYLIC-ACIDS; DIRECT ALPHA-ARYLATION; TRANSITION-METAL-FREE; P BOND FORMATION; Homogeneous catalysis; Photocatalysis; Photoredox catalysis; Retrosynthesis; Synthetic methods
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Depositing User: Petra Gürster
Date Deposited: 09 Apr 2021 05:18
Last Modified: 09 Apr 2021 05:18
URI: https://pred.uni-regensburg.de/id/eprint/44934

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