Dehmel, Maximilian and Vass, Valentin and Prock, Lukas and Goerls, Helmar and Kretschmer, Robert (2020) Synthesis and Coordination Chemistry of 3,4-Ethylene-Bridged 1,1,2,5-Tetrasubstituted Biguanides. INORGANIC CHEMISTRY, 59 (5). pp. 2733-2746. ISSN 0020-1669, 1520-510X
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The synthesis of 3,4-ethylene-bridged 1,1,2,5-tetrasubstituted biguanides is reported, which are accessible by three alternative routes. Exemplary molecular structures of the ligand and an observed side product have been elucidated by X-ray diffraction analysis. Mono- and dinuclear complexes of the biguanide in both its neutral and monoanionic forms were obtained, including examples of aluminum, copper, magnesium, potassium, tin, and zinc, indicating a versatile coordination behavior, as evidenced by means of single-crystal X-ray diffraction analysis.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | POLYMER NETWORKS; COMPLEXES; LIGAND; NICKEL(II); REACTIVITY; CATALYST; HYDRIDES; CO2; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 29 Mar 2021 09:36 |
| Last Modified: | 29 Mar 2021 09:36 |
| URI: | https://pred.uni-regensburg.de/id/eprint/44969 |
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