Redox Noninnocent Nature of Acridine-Based Pincer Complexes of 3d Metals and C-C Bond Formation

Daw, Prosenjit and Kumar, Amit and Oren, Dror and Espinosa-Jalapa, Noel Angel and Srimani, Dipankar and Diskin-Posner, Yael and Leitus, Gregory and Shimon, Linda J. W. and Carmieli, Raanan and Ben-David, Yehoshoa and Milstein, David (2020) Redox Noninnocent Nature of Acridine-Based Pincer Complexes of 3d Metals and C-C Bond Formation. ORGANOMETALLICS, 39 (2). pp. 279-285. ISSN 0276-7333, 1520-6041

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Abstract

Acridine-based PNP pincer complexes have been previously utilized for several environmentally benign catalytic processes. In light of the recent growth in interest in base-metal catalysis, we report here the synthesis of acridine-PNP pincer complexes of Ni, Co, Fe, and Mn. We also report here the noninnocent redox nature of these complexes that results in the dimerization of pincer complexes by forming a C-C bond at the C9 position of the acridine ring.

Item Type: Article
Uncontrolled Keywords: LIGAND COOPERATION; PRIMARY AMINES; HYDROGENATION; IRON; RUTHENIUM; ACTIVATION; CATALYSIS; WATER; CONVERSION; EFFICIENT;
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Anorganische Chemie
Depositing User: Dr. Gernot Deinzer
Date Deposited: 01 Apr 2021 08:17
Last Modified: 01 Apr 2021 08:17
URI: https://pred.uni-regensburg.de/id/eprint/45315

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