Moussa, Mehdi Elsayed and Schiller, Jana and Seidl, Michael and Shelyganov, Pavel A. and Scheer, Manfred (2021) Discrete and polymeric organometallic-organic assemblies based on the diarsene complex [(Cp)(2)Mo-2(CO)(4)(mu,eta(2)-As-2)], AgPF6 and N-donor organic molecules. NEW JOURNAL OF CHEMISTRY, 45 (4). pp. 1800-1804. ISSN 1144-0546, 1369-9261
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Three-component reactions of the organometallic diarsene complex [Cp2Mo2(CO)(4)(mu,eta(2)-As-2)] (B) (Cp = C5H5) with AgPF6 in the presence of different N-donor linkers are presented. Depending on the organic linker used, discrete [{(eta(2)-B)(2)Ag}(2)(L1)][PF6](2) (1) and [{(eta(2)-B)(2)Ag}(2)(L2)][PF6](2) (2) organometallic-organic hybrid assemblies and polymeric [{(eta(2)-B)Ag}(L3)](n)[PF6](n) (3), [{(eta(1):eta(2)-B)(2)(CH3CN)(2)Ag-2}(L4)](n)[PF6](2n) (4), [{(eta(1):eta(2)-B)(2)(CH3CN)(2)Ag-2}(L5)](n)[PF6](2n) (5) and [{(eta(1):eta(2)-B)(2)(eta(1):eta(1)-B)Ag-2}(L5)](n)[PF6](2n) (6) ones are obtained. 4-6 possess unique structures in which Ag center dot center dot center dot Ag interactions occur.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | COORDINATION CHEMISTRY; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 19 Jul 2022 08:10 |
| Last Modified: | 19 Jul 2022 08:10 |
| URI: | https://pred.uni-regensburg.de/id/eprint/45784 |
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