From a P-4 butterfly scaffold to cyclo- and catena-P-4 units

Mueller, Julian and Balazs, Gabor and Scheer, Manfred (2021) From a P-4 butterfly scaffold to cyclo- and catena-P-4 units. CHEMICAL COMMUNICATIONS, 57 (18). pp. 2257-2260. ISSN 1359-7345, 1364-548X

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Abstract

The reactivity of [{Cp ''' Fe(CO)(2)}(2)(mu,eta(1 : 1)-P-4)] (1) towards half-sandwich complexes of Ru(ii), Rh(iii), and Ir(iii) is studied. The coordination of these Lewis acids leads to a rearrangement of the P-4 butterfly unit to form complexes with either an aromatic cyclo-P4R2 unit (R = Cp ''' Fe(CO)(2)) or a catena-tetraphosphaene entity.

Item Type: Article
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Depositing User: Dr. Gernot Deinzer
Date Deposited: 07 Jul 2022 04:39
Last Modified: 07 Jul 2022 04:39
URI: https://pred.uni-regensburg.de/id/eprint/45808

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