Structural Chemistry of Giant Metal Based Supramolecules

Virovets, Alexander V. and Peresypkina, Eugenia and Scheer, Manfred (2021) Structural Chemistry of Giant Metal Based Supramolecules. CHEMICAL REVIEWS, 121 (23). pp. 14485-14554. ISSN 0009-2665, 1520-6890

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Abstract

The review presents a bird-eye view on the state of research in the field of giant nonbiological discrete metal complexes and ions of nanometer size, which are structurally characterized by means of single-crystal X-ray diffraction, using the crystal structure as a common key feature. The discussion is focused on the main structural features of the metal clusters, the clusters containing compact metal oxide/hydroxide/chalcogenide core, ligand-based metal-organic cages, and supramolecules as well as on the aspects related to the packing of the molecules or ions in the crystal and the methodological aspects of the single-crystal neutron and X-ray diffraction of these compounds.

Item Type: Article
Uncontrolled Keywords: X-RAY-STRUCTURE; HIGH-NUCLEARITY CARBONYL; CRYSTAL-STRUCTURE; CHALCOGENIDE CLUSTERS; ORGANIC POLYHEDRA; SINGLE-CRYSTAL; SPONTANEOUS RESOLUTION; NEUTRON-DIFFRACTION; GOLD CLUSTERS; COORDINATION POLYMERS
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Depositing User: Petra Gürster
Date Deposited: 16 Dec 2022 07:16
Last Modified: 16 Dec 2022 07:16
URI: https://pred.uni-regensburg.de/id/eprint/45817

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