Engl, Sebastian and Reiser, Oliver (2021) Catalyst-Free Visible-Light-Mediated Iodoamination of Olefins and Synthetic Applications. ORGANIC LETTERS, 23 (14). pp. 5581-5586. ISSN 1523-7060, 1523-7052
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Herein we report a catalyst- and metal-free visible-light-mediated protocol enabling the iodoamination of miscellaneous olefins. This protocol is characterized by high yields under environmentally benign reaction conditions utilizing commercially available substrates and a green and biodegradable solvent. Furthermore, the protocol allows for late-stage functionalization of bioactive molecules and can be scaled to gram quantities of product, which offers manifold possibilities for further transformations, including morpholine, piperidine, pyrrolidine, and aziridine synthesis.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ALKENES; NITROGEN; AMINOBROMINATION; AMINES; AMINOHALOGENATION; AMINOCHLORINATION |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 07 Jul 2022 06:29 |
| Last Modified: | 07 Jul 2022 06:29 |
| URI: | https://pred.uni-regensburg.de/id/eprint/45855 |
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