Hierlmeier, Gabriele and Uttendorfer, Maria K. and Wolf, Robert (2021) Di-tert-butyldiphosphatetrahedrane as a building block for phosphaalkenes and phosphirenes. CHEMICAL COMMUNICATIONS, 57 (19). pp. 2356-2359. ISSN 1359-7345, 1364-548X
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The remarkable 'mixed' diphosphatetrahedrane (tBuCP)(2) (1) - which is both the elusive dimeric form of the phosphaalkyne tBuCP and an isolobal analogue of the important industrial feedstock P-4 - was recently isolated for the first time; however, its chemistry remains unexplored. Herein we report that treatment of 1 with various N-heterocyclic carbenes readily yields unusual, unsaturated organophosphorus motifs. These results demonstrate the significant potential of 1 as a building block for the synthesis of previously unknown organophosphorus compounds.
| Item Type: | Article |
|---|---|
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Robert Wolf |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 07 Jul 2022 06:51 |
| Last Modified: | 07 Jul 2022 06:51 |
| URI: | https://pred.uni-regensburg.de/id/eprint/45858 |
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