Moussa, Mehdi Elsayed and Marquardt, Christian and Hegen, Oliver and Seidl, Michael and Scheer, Manfred (2021) A new family of silver(i) complexes stabilised by the phosphanylborane (C6H5)(2)PBH2 center dot N(CH3)(3). NEW JOURNAL OF CHEMISTRY, 45 (33). pp. 14916-14919. ISSN 1144-0546, 1369-9261
Full text not available from this repository. (Request a copy)Abstract
The reactions of the phosphanylborane Ph2PBH2 center dot NMe3 (L) with Ag[FAl{OC6F10(C6F5)}(3)] (Ag[FAl]) and AgBF4 are studied. The first reaction allowed for the synthesis of the coordination compounds [Ag(Ph2P-BH2 center dot NMe3)(CH3CN)][FAl] (1), [Ag(Ph2P-BH2 center dot NMe3)(2)][FAl] (2) and [Ag(Ph2P-BH2 center dot NMe3)(3)][FAl] (3), while the second reaction afforded the one-dimensional coordination polymer [Ag(Ph2P-BH2 center dot NMe3)](n)[BF4](n) (4). Compounds 1-4 are the first reported Ag(i) complexes stabilised by phosphanylboranes.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | COORDINATION POLYMERS; PHOSPHINE COMPLEXES; LIGAND; BEHAVIOR; CHAINS; 1'-(DIPHENYLPHOSPHINO)-1-CYANOFERROCENE; CP2MO2(CO)(4)(ETA(2)-P-2); DIMENSIONALITY; CHEMISTRY; CATIONS |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 07 Jul 2022 07:49 |
| Last Modified: | 07 Jul 2022 07:49 |
| URI: | https://pred.uni-regensburg.de/id/eprint/45879 |
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