Shenderovich, Ilya G. (2021) Actual Symmetry of Symmetric Molecular Adducts in the Gas Phase, Solution and in the Solid State. SYMMETRY-BASEL, 13 (5): 756. ISSN 2073-8994
Full text not available from this repository. (Request a copy)Abstract
This review discusses molecular adducts, whose composition allows a symmetric structure. Such adducts are popular model systems, as they are useful for analyzing the effect of structure on the property selected for study since they allow one to reduce the number of parameters. The main objectives of this discussion are to evaluate the influence of the surroundings on the symmetry of these adducts, steric hindrances within the adducts, competition between different noncovalent interactions responsible for stabilizing the adducts, and experimental methods that can be used to study the symmetry at different time scales. This review considers the following central binding units: hydrogen (proton), halogen (anion), metal (cation), water (hydrogen peroxide).
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | HYDROGEN-BOND GEOMETRIES; NMR CHEMICAL-SHIFTS; AB-INITIO; NEUTRON-DIFFRACTION; X-RAY; SPECTRAL PROPERTIES; CRYSTAL-STRUCTURES; ACID-BASE; COMPLEXES; ISOTOPE; hydrogen bonding; noncovalent interactions; isotope effect; cooperativity; water; organometallic complexes; NMR; DFT |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie |
| Depositing User: | Petra Gürster |
| Date Deposited: | 20 Dec 2022 07:08 |
| Last Modified: | 20 Dec 2022 07:08 |
| URI: | https://pred.uni-regensburg.de/id/eprint/46068 |
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