Light-Induced Single-Electron Transfer Processes involving Sulfur Anions as Catalysts

Wang, Shun and Wang, Hua and Koenig, Burkhard (2021) Light-Induced Single-Electron Transfer Processes involving Sulfur Anions as Catalysts. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 143 (38). pp. 15530-15537. ISSN 0002-7863, 1520-5126

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Abstract

Photoredox catalysis has evolved as an attractive approach to enable a wide variety of chemical reactions with high selectivity under mild conditions. The development of novel photocatalytic systems is key to obtaining new reactivity and improving their catalytic performances. In this context, cost-effective organic anion-based photocatalysts have recently attracted increasing interest. In particular, sulfur-based anionic catalysts are of interest due to their unique redox properties. This Perspective highlights and discusses recent advances in light-induced single-electron-transfer processes directly involving sulfur anions as catalysts. The content of this Perspective is organized along the different photoinduced electron-transfer pathways between catalysts and substrates.

Item Type: Article
Uncontrolled Keywords: TRISULFUR RADICAL-ANION; PHOTOREDOX CATALYSIS; CHEMISTRY; MECHANISM; ACYL; DEOXYGENATION; ARYLATION; XANTHATES; ALKYL
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Depositing User: Petra Gürster
Date Deposited: 20 Dec 2022 09:35
Last Modified: 20 Dec 2022 09:35
URI: https://pred.uni-regensburg.de/id/eprint/46140

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