Haimerl, Maria and Grassl, Christian and Seidl, Michael and Piesch, Martin and Scheer, Manfred (2021) Conversion of E-4 (E-4=P-4, As-4, AsP3) by Ni(0) and Ni(I) Synthons - A Comparative Study. CHEMISTRY-A EUROPEAN JOURNAL, 27 (72). pp. 18129-18134. ISSN 0947-6539, 1521-3765
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The reactivity of white phosphorus and yellow arsenic towards two different nickel nacnac complexes is investigated. The nickel complexes [((LNi)-Ni-1)(2)tol] (1, L-1=[{N((C6H3Pr2)-Pr-i-2,6)C(Me)}(2)CH](-)) and [K-2][((LNi)-Ni-1)(2)(mu,eta(1 : 1)-N-2)] (6) were reacted with P-4, As-4 and the interpnictogen compound AsP3, respectively, yielding the homobimetallic complexes [((LNi)-Ni-1)(2)(mu-eta(2),kappa(1):eta(2),kappa(1)-E-4)] (E=P (2 a), As (2 b), AsP3 (2 c)), [((LNi)-Ni-1)(2)(mu,eta(3 : 3)-E-3)] (E=P (3 a), As (3 b)) and [K@18-c-6(thf)(2)][(LNi)-Ni-1(eta(1 : 1)-E-4)] (E=P (7 a), As (7 b)), respectively. Heating of 2 a, 2 b or 2 c also leads to the formation of 3 a or 3 b. Furthermore, the reactivity of these compounds towards reduction agents was investigated, leading to [K-2][((LNi)-Ni-1)(2)(mu,eta(2 : 2)-P-4)] (4) and [K@18-c-6(thf)(3)][((LNi)-Ni-1)(2)(mu,eta(3 : 3)-E-3)] (E=P (5 a), As (5 b)), respectively. Compound 4 shows an unusual planarization of the initial Ni2P4-prism. All products were comprehensively characterized by crystallographic and spectroscopic methods.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | CYCLO-TRIPHOSPHORUS; WHITE PHOSPHORUS; NICKEL-COMPLEXES; P-4 ACTIVATION; RARE-EARTH; DINITROGEN; REACTIVITY; COBALT; LIGAND; REDUCTION; activation; reduction; transition metal; white phosphorus; yellow arsenic |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 05 Jul 2022 06:37 |
| Last Modified: | 05 Jul 2022 06:37 |
| URI: | https://pred.uni-regensburg.de/id/eprint/46156 |
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