Grundl, G. and Mueller, R. and Kunz, Werner (2021) Salt effects on liquid-liquid equilibria in the ternary water/n-butanol/HMF system and solvent effects on HMF separation from water. JOURNAL OF MOLECULAR LIQUIDS, 325: 114551. ISSN 0167-7322, 1873-3166
Full text not available from this repository. (Request a copy)Abstract
Experimental liquid-liquid equilibrium data of the ternary system composed of water, n-butanol and 5-hydroxymethyffurfural (HMF) as well as of quatemaiy systems containing water, n-butanol, HMF and salts are presented at 298.15 K and 1 bar. Salt effects of KCl, Na2SO4, Al-2(SO4)(3), NH4NO3, CH3COONa, C2H5COONa and C3H7COONa were studied. The quaternary system water/n-butanol/HMF/Na2SO4 was also investigated at 303.15 K due to the maximum Na2SO4 solubility in water near this temperature. HMF distribution ratios (D-w(HMF)) and HMF separation factors (alpha(w)(FIMF,water)) were the parameters used to evaluate the salting-out effects on HMI and the extraction selectivity. The association behaviour of HMF in binary water/HMF and ternary water/HMF/LiCl mixtures was studied by means of DIS. The influence of different extractive solvents on the HMF distribution behaviour and on the HMF extraction selectivity was evaluated using corresponding LLE data from literature. (C) 2020 Elsevier B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ; Liquid-liquid equilibrium; 5-Hydroxymethylfurfural; Salt effects; Distribution ratio; Separation factor; Highly concentrated LiCl solution |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > Prof. Dr. Werner Kunz |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 09 Aug 2022 08:02 |
| Last Modified: | 09 Aug 2022 08:02 |
| URI: | https://pred.uni-regensburg.de/id/eprint/46172 |
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