Kaur, Jaspreet and Shahin, Ahmed and Barham, Joshua P. (2021) Photocatalyst-Free, Visible-Light-Mediated C(sp(3))-H Arylation of Amides via a Solvent-Caged EDA Complex. ORGANIC LETTERS, 23 (6). pp. 2002-2006. ISSN 1523-7060, 1523-7052
Full text not available from this repository. (Request a copy)Abstract
A photocatalyst-free and mild visible light photochemical procedure for C(sp(3))-H arylation of amides is described. The reaction proceeds via an electron donor-acceptor (EDA) complex between an electron-rich arene substrate and electron-poor persulfate oxidant. C(sp(3))-H arylation of the amide occurs selectively with the most electron-rich arene of the substrate. Mechanistic studies corroborate the reaction taking place in a solvent cage holding components in a close proximity.
| Item Type: | Article |
|---|---|
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 28 Jul 2022 10:14 |
| Last Modified: | 28 Jul 2022 10:14 |
| URI: | https://pred.uni-regensburg.de/id/eprint/46221 |
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