Margeson, Matthew J. and Seeberger, Felix and Kelly, John A. and Leitl, Julia and Coburger, Peter and Szlosek, Robert and Mueller, Christian and Wolf, Robert (2021) Expedient Hydrofunctionalisation of Carbonyls and Imines Initiated by Phosphacyclohexadienyl Anions. CHEMCATCHEM, 13 (17). pp. 3761-3764. ISSN 1867-3880, 1867-3899
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The ability of phosphacyclohexadienyl anions [Li(1-R-PC5Ph3H2)] [R=Me (1 a), nBu (1 b), tBu (1 c), Ph (1 d) and CH2SiMe3 (1 e)] to initiate hydrofunctionalisation reactions was investigated and compared with simple, commercially available compounds, such as LiOtBu, KOtBu and nBuLi. All compounds are expedient catalysts for the hydroboration of a wide scope of substrates, ranging from aldehydes to imines and esters. In the hydroboration of carbon dioxide, however, only our system was observed to efficiently produce the desired methanol equivalents.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | MAIN-GROUP ELEMENTS; CATALYTIC HYDROBORATION; HYDROSILYLATION; KETONES; REDUCTION; ALDEHYDES; Carbon dioxide reduction; Hydrofunctionalisation; Main group catalysis; Phosphinine; Phosphorus |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Robert Wolf |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 17 Aug 2022 12:06 |
| Last Modified: | 17 Aug 2022 12:06 |
| URI: | https://pred.uni-regensburg.de/id/eprint/46646 |
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