Natarajan, Palani and Koenig, Burkhard (2021) Excited-State 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone (DDQ*) Initiated Organic Synthetic Transformations under Visible-Light Irradiation. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2021 (15). pp. 2145-2161. ISSN 1434-193X, 1099-0690
Full text not available from this repository. (Request a copy)Abstract
The one-electron oxidizing capacity of 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) improves significantly by visible-light excitation. The exited-state DDQ (DDQ*) even converts benzene, fluoroarenes, heteroarenes, benzyls, and olefins into their corresponding radical cations as well as chloride and other anions into their radicals. These reactive intermediates have been utilized for the generation of C-C and C-X (N, O, or Cl) bonds in the synthesis of valuable organic compounds and natural products. This mini review provides an overview of such DDQ*-initiated organic transformations with their scope and limitations and discusses the proposed reactions mechanisms.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ELECTRON-TRANSFER; PHOTOREDOX CATALYSIS; P-BENZOQUINONE; BENZENE; HYDROXYLATION; OXIDATION; ARENES; 2,3-DICHLORO-5,6-DICYANO-P-BENZOQUINONE; REACTIVITY; COMPLEXES; Cross coupling; DDQ; Dehydrogenative coupling; Photooxidation; Quinones |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König |
| Depositing User: | Petra Gürster |
| Date Deposited: | 10 Jan 2023 11:16 |
| Last Modified: | 10 Jan 2023 11:16 |
| URI: | https://pred.uni-regensburg.de/id/eprint/46767 |
Actions (login required)
 |
View Item |
