Giusti, Leonardo and Landaeta, Vanessa R. and Vanni, Matteo and Kelly, John A. and Wolf, Robert and Caporali, Maria (2021) Coordination chemistry of elemental phosphorus. COORDINATION CHEMISTRY REVIEWS, 441: 213927. ISSN 0010-8545, 1873-3840
Full text not available from this repository. (Request a copy)Abstract
This review comprehensively covers the coordination chemistry of elemental phosphorus during the years 2011-2020. The main part is dedicated to the activation of white phosphorus mediated by early and late transition metals and its subsequent reactivity once in the coordination sphere of a metal. The burgeoning interest towards early TMs has opened the way to new coordination topologies and types of reactivity. Meanwhile, the coordination chemistry of P4 towards late transition metal elements has also attracted significant attention. Numerous studies have targeted transformations of P4-derived phosphorus ligands and the subsequent release of said ligand fragments. The final part of this review focuses on the black allotrope of phosphorus, which offers a polydentate phosphorus surface able to interact with transition metals forming new functionalized 2D materials. (C) 2021 The Authors. Published by Elsevier B.V.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | TRIPLE-DECKER COMPLEXES; ANIONIC DIPHOSPHORUS COMPLEX; ULTRATHIN BLACK PHOSPHORUS; SYMMETRICAL P-4 CLEAVAGE; WHITE PHOSPHORUS; CYCLO-TRIPHOSPHORUS; METAL-COMPLEXES; TETRAHEDRO-TETRAPHOSPHORUS; SANDWICH COMPLEXES; DYNAMIC-BEHAVIOR |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Robert Wolf |
| Depositing User: | Petra Gürster |
| Date Deposited: | 10 Jan 2023 11:10 |
| Last Modified: | 10 Jan 2023 11:10 |
| URI: | https://pred.uni-regensburg.de/id/eprint/46786 |
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