Sun, Xiaofei and Singh, Akhil Kumar and Yadav, Ravi and Jin, Da and Haimerl, Maria and Scheer, Manfred and Roesky, Peter W. (2022) Triple-decker complexes incorporating three distinct deck architectures. CHEMICAL COMMUNICATIONS, 58 (5). pp. 673-676. ISSN 1359-7345, 1364-548X
Full text not available from this repository. (Request a copy)Abstract
The reactivity of the dilithioplumbole ([Li-2(thf)(2)(mu,eta(5)-L-Pb)], L-Pb = 1,4-bis-tert-butyl-dimethylsilyl-2,3-bis-phenyl-plumbolyl) towards the reactive pnictogen precursors P-4, pentaphosphaferrocene, and pentaarsaferrocene ([Cp*Fe(eta(5)-E-5)] (Cp* = eta(5)-C5Me5, E = P, As)) is reported. The reaction with P-4 afforded a phospholyl lithium complex, via lead-phosphorus exchange, while the reactions with [Cp*Fe(eta(5)-E-5)] yielded the first examples of Pb-Fe-Li heterotrimetallic triple-decker polypnictogenides with three different deck motifs.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | LIGAND; SANDWICH; IRON; CP-ASTERISK-FE(ETA(5)-P-5); POLYPNICTIDES; POLYARSENIDES; DIMERIZATION; REACTIVITY; BEARING; BULKY; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 12 Sep 2022 05:41 |
| Last Modified: | 12 Sep 2022 05:41 |
| URI: | https://pred.uni-regensburg.de/id/eprint/47059 |
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