Fabrication of a Solution-Processed White Light Emitting Diode Containing a Single Dimeric Copper(I) Emitter Featuring Combined TADF and Phosphorescence

Cheng, Gang and Zhou, Dongling and Monkowius, Uwe and Yersin, Hartmut (2021) Fabrication of a Solution-Processed White Light Emitting Diode Containing a Single Dimeric Copper(I) Emitter Featuring Combined TADF and Phosphorescence. MICROMACHINES, 12 (12): 1500. ISSN , 2072-666X

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Abstract

Luminescent copper(I) complexes showing thermally activated delayed fluorescence (TADF) have developed to attractive emitter materials for organic light emitting diodes (OLEDs). Here, we study the brightly luminescent dimer Cu2Cl2(P & AND;N)(2) (P & AND;N = diphenylphosphanyl-6-methyl-pyridine), which shows both TADF and phosphorescence at ambient temperature. A solution-processed OLED with a device structure ITO/PEDOT:PSS/PYD2: Cu2Cl2(P & AND;N)(2)/DPEPO (10 nm)/TPBi (40 nm)/LiF (1.2 nm)/Al (100 nm) shows warm white emission with moderate external quantum efficiency (EQE). Methods for EQE increase strategies are discussed.

Item Type: Article
Uncontrolled Keywords: ACTIVATED DELAYED FLUORESCENCE; CU(I) COMPLEXES; TRIPLET EMITTERS; CU-I; EMISSION; DESIGN; BLUE; EFFICIENCY; ELECTROLUMINESCENCE; LIGANDS; dimeric copper(I) complexes; P boolean AND N phosphine ligands; combined thermally activated delayed fluorescence and phosphorescence; thermally activated delayed fluorescence (TADF); combined singlet and triplet harvesting; organic light emitting diodes (OLEDs); white emission; white light emitting OLED (WOLED)
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin
Depositing User: Dr. Gernot Deinzer
Date Deposited: 14 Sep 2022 12:06
Last Modified: 14 Sep 2022 12:06
URI: https://pred.uni-regensburg.de/id/eprint/47469

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