Eitel, Michael and Zinad, Dhafer S. and Schollmeyer, Dieter and Gross, Harald and Koch, Pierre (2021) Selective mono-de-O-acetylation of the per-O-acetylated brasilicardin carbohydrate side chain. CARBOHYDRATE RESEARCH, 504: 108312. ISSN 0008-6215, 1873-426X
Full text not available from this repository. (Request a copy)Abstract
Methanol dried over powdered 4 angstrom molecular sieves can be used for a selective mono-de-O-acetylation of the phenolic acetyl group of the per -O-acetyl protected brasilicardin A carbohydrate side chain. This reaction opens a practical procedure for a synthetic access to derivates of the immunosuppressive and cytotoxic natural product brasilicardin A.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | Brasilicardin A; Natural products; Immunosuppressant; Molecular sieves; Carbohydrates; Deacetylation |
| Subjects: | 500 Science > 540 Chemistry & allied sciences 600 Technology > 615 Pharmacy |
| Divisions: | Chemistry and Pharmacy > Institute of Pharmacy > Pharmaceutical/Medicinal Chemistry II (Prof. Buschauer) |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 13 Sep 2022 05:42 |
| Last Modified: | 13 Sep 2022 05:42 |
| URI: | https://pred.uni-regensburg.de/id/eprint/47701 |
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