Barthel, Josef and Neueder, Roland and Poepke, Herbert and Wittmann, Harald (1999) Osmotic coefficients and activity coefficients of nonaqueous electrolyte solutions. Part 2. Lithium perchlorate in the aprotic solvents acetone, acetonitrile, dimethoxyethane, and dimethylcarbonate. JOURNAL OF SOLUTION CHEMISTRY, 28 (5). pp. 489-503. ISSN 0095-9782,
Full text not available from this repository. (Request a copy)Abstract
Vapor pressure lowering by the addition of lithium perchlorate to the aprotic solvents acetone (0.02-0.6 m), acetonitrile (0.05-1.2 m), dimethoxyethane (0.02-0.4 m), and dimethylcarbonate (0.03-1.8 m) was measured at 25 degrees C with high precision. The experimental data for the corresponding osmotic coefficients are compared to those obtained from the Pitzer equations and chemical model calculations. Mean activity coefficients are derived from the osmotic coefficients.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | VAPOR-PRESSURE MEASUREMENTS; THERMODYNAMICS; METHANOL; SALTS; osmotic coefficient; activity coefficient; aprotic solvents; Pitzer equation; chemical model |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 25 Oct 2022 10:00 |
| Last Modified: | 25 Oct 2022 10:00 |
| URI: | https://pred.uni-regensburg.de/id/eprint/48289 |
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