Anikin, Valeriy F. and Veduta, Vera V. and Merz, Andreas (1999) Stereochemistry of the addition of bromine to acenaphthylene derivatives: Substituent and solvent effects. MONATSHEFTE FUR CHEMIE, 130 (5). pp. 681-690. ISSN 0026-9247,
Full text not available from this repository.Abstract
Addition of bromine to acenaphthylene and 5-bromoacenaphthylene in aprotic solvents of different polarity is not stereospecific: both trans and cis isomers of the corresponding 1,2-dibromides are formed. In general, the relative proportion of syn addition increases with decreasing solvent polarity; the highest percentage of cis products is observed in 1,4-dioxane. The stereochemistry of bromine addition to nine additional 3-, 5-, and 5,6-substituted acenaphthylenes in dioxane is reported. A number of new cis-1,2-dibromoacenaphthenes have been isolated for the first time.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | BROMONIUM; PRODUCT; ION; acenaphthene derivatives; electrophilic addition; stereoselectivity; solvent effects |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 25 Oct 2022 12:54 |
| Last Modified: | 25 Oct 2022 12:54 |
| URI: | https://pred.uni-regensburg.de/id/eprint/48298 |
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