Brunner, Henri and Mijolovic, Darijo (1999) Enantioselective catalysis - Part 129. A new rhodium(I) complex with a mu(2)-H bridged Cp2WH2 ligand. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 577 (2). pp. 346-350. ISSN 0022-328X,
Full text not available from this repository. (Request a copy)Abstract
The optically active complex {[(-)-diop]Rh(mu(2)-H)(2)WCp2}PF6 was prepared and characterized. In four different models of enantioselective catalysis the complex gave the same enantioselectivity as the catalysts [Rh(cod)Cl](2)/(-)-diop and [Rh(cod)Cl](2)/(-)-diop/Cp2WH2. (C) 1999 Elsevier Science S.A. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | TRANSITION-METAL COMPLEXES; ASYMMETRIC HYDROGENATION; CHIRAL DIPHOSPHINE; HYDROSILYLATION; MECHANISM; KETONES; SYSTEM; ACIDS; enantioselectivity; catalysis; optical activity |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Henri Brunner |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 08 Nov 2022 14:08 |
| Last Modified: | 08 Nov 2022 14:08 |
| URI: | https://pred.uni-regensburg.de/id/eprint/48409 |
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