Kunkely, Horst and Vogler, Arnd (1999) Photooxidation of Rh(PPh3)(2)(CS)Cl induced by metal-to-ligand charge transfer excitation. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 577 (2). pp. 358-360. ISSN 0022-328X,
Full text not available from this repository. (Request a copy)Abstract
The longest-wavelength absorption of Rh-I(PPh3)(2)(CS)Cl at lambda(max) = 452 nm is assigned to a metal-to-ligand charge transfer (MLCT) transition which terminates at the pi* orbital of the thiocarbonyl ligand. MLCT excitation of the complex in CH2Cl2 initiates a photooxidation which finally leads to Rh-III(PPh3)(2)(CS)Cl-3 as a stable photoproduct with phi = 0.003 at lambda(irr) = 436 nm. (C) 1999 Elsevier Science S.A. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | FLASH-PHOTOLYSIS; THIOCARBONYL COMPLEXES; REACTION DYNAMICS; RHCL(PPH3)2; RHODIUM(I); IRIDIUM(I); SPECTRA; photochemistry; charge transfer; rhodium; thiocarbonyl |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 08 Nov 2022 14:16 |
| Last Modified: | 08 Nov 2022 14:16 |
| URI: | https://pred.uni-regensburg.de/id/eprint/48410 |
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