Enantioselective catalyses; 126: Axially chiral N,N-ligands with binaphthyl/bipyridyl structure

Brunner, Henri and Olschewski, G. and Nuber, B. (1999) Enantioselective catalyses; 126: Axially chiral N,N-ligands with binaphthyl/bipyridyl structure. SYNTHESIS-STUTTGART (3). pp. 429-434. ISSN 0039-7881,

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Abstract

N,N-Ligands with combined binaphthyl/bipyridyl structure were synthesized by palladium-catalyzed coupling of 1-naphthylboronic acids with 1-halogenoisoquinoline derivates and with 4-bromo-2-(2-pyridyl)naphtho[2,3-d]-1,3-oxazole. Racemic 1-(2-methoxy-1-naphthyl)-3-(2-pyridyl)isoquinoline was resolved via diastereomeric salt formation with (-)-3-bromocamphor-8-sulfonic acid and the absolute configuration was determined by X-ray analysis.

Item Type: Article
Uncontrolled Keywords: ASYMMETRIC CATALYSIS; REDUCING AGENTS; LIGANDS; binaphthyl; bipyridyl; Suzuki coupling; axial chirality; absolute configuration
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Henri Brunner
Depositing User: Dr. Gernot Deinzer
Date Deposited: 15 Nov 2022 15:03
Last Modified: 15 Nov 2022 15:03
URI: https://pred.uni-regensburg.de/id/eprint/48504

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