Brunner, Henri and Muschiol, Manfred and Neuhierl, Thomas and Nuber, Bernhard (1999) Copper complexes with the ligand [Cp2MoH2]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 54 (3). pp. 337-340. ISSN 0932-0776,
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The reaction of CuCl with [Cp2MoH2] yields the complex [Cu(Cp2MoH2)(2)Cl]. An X-ray structure analysis shows that the coordination of the copper(I) ion by two [Cp2MoH2] ligands and the chloride ion is pseudo-trigonal planar. The hydride ligands were located by using difference Fourier methods. A manifold of reactions took place when an aqueous solution of CuSO4 was treated with a solution of [Cp2MoH2] in dichloromethane in a 1:2 molar ratio. The X-ray structure analysis established a polymeric structure of the complex [Cu(Cp2MoH2)(2)Cu(Cp2MoH2)SO4](n) with two different copper centers.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ; copper; molybdenum; X-ray data |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Henri Brunner |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 15 Nov 2022 15:23 |
| Last Modified: | 15 Nov 2022 15:23 |
| URI: | https://pred.uni-regensburg.de/id/eprint/48507 |
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