Kunkely, Horst and Vogler, Arnd (1999) Photolysis of the ion pair [eta(7)-C7H7Mo(CO)(3)]+BPh4- induced by outer sphere charge transfer excitation. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 572 (1). pp. 131-133. ISSN 0022-328X, 1872-8561
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The electronic spectrum of the ion pair [eta(7)-C7H7Mo(CO)(3)]+BPh4- in CH2Cl2 shows an outer sphere charge transfer (OSCT) absorption at lambda(max) = 370 nm. OSCT excitation yields [(eta(6)-C7H7Ph)Mo(CO)(3)] with phi = 0.02 at lambda = 405 nm. (C) 1999 Elsevier Science S.A. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | COMPLEXES; PHOTOCHEMISTRY; photochemistry; charge transfer; molybdenum; tropylium |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 22 Nov 2022 15:34 |
| Last Modified: | 22 Nov 2022 15:34 |
| URI: | https://pred.uni-regensburg.de/id/eprint/48588 |
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