Osmotic coefficients and activity coefficients of nonaqueous electrolyte solutions. part 4. Lithium bromide, tetrabutylammonium bromide, and tetrabutylammonium perchlorate in acetone

Barthel, Josef and Neueder, Roland and Poepke, Herbert and Wittmann, Harald (1999) Osmotic coefficients and activity coefficients of nonaqueous electrolyte solutions. part 4. Lithium bromide, tetrabutylammonium bromide, and tetrabutylammonium perchlorate in acetone. JOURNAL OF SOLUTION CHEMISTRY, 28 (12). pp. 1277-1287. ISSN 0095-9782,

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Abstract

Vapor pressure lowering by the addition of lithium bromide (0.03-0.8m), tetrabutylammonium bromide (0.01 - 0.8m), and tetrabutylammonium perchlorate (0.02-3.6m) to acetone was measured at 25 degrees C with high precision. The experimental data of the corresponding osmotic coefficients are compared to those obtained by the use of Pitzer equations and chemical model calculations. Mean activity coefficients are derived from the osmotic coefficients.

Item Type: Article
Uncontrolled Keywords: VAPOR-PRESSURE MEASUREMENTS; THERMODYNAMICS; METHANOL; SALTS; osmotic coefficient; activity coefficient; electrolyte solution; acetone; Pitzer equation; chemical model; lithium bromide; tetrabutylammonium bromide; tetrabutylammonium perchlorate
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie
Depositing User: Dr. Gernot Deinzer
Date Deposited: 06 Dec 2022 12:58
Last Modified: 06 Dec 2022 12:58
URI: https://pred.uni-regensburg.de/id/eprint/48799

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