Demel, Roswitha and Doetterl, Eleonore and Merz, Andreas (1999) Catalytic electrochemical reduction of 1,2-dibromocyclohexane derivatives at carbon electrodes modified with cobalt porphyrin siloxane films. ACTA CHEMICA SCANDINAVICA, 53 (11). pp. 1038-1042. ISSN 0904-213X,
Full text not available from this repository.Abstract
The electrochemical reduction of trans-1,2-dibromocylohexanes is catalyzed effectively by Co(II) porphyrins at potentials greater than or equal to 1 V positive of the uncatalyzed case. With siloxane films on carbon electrodes containing a specially designed, diethylene glycol spacered Co-porphyrin, high catalytic currents are observed. Preparative current yields of 65% on a mmol scale are obtained with average calculated catalyst turnover numbers of ca. 5000.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | REDOX CATALYSIS; OXIDATION; KINETICS; POLYMERS; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 13 Dec 2022 07:02 |
| Last Modified: | 13 Dec 2022 07:02 |
| URI: | https://pred.uni-regensburg.de/id/eprint/48856 |
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