New indigoid compounds by reduction of bis-imidoylchlorides of oxalic acid - A further evidence for dimeric isocyanides?

Wenzel, Matthias and Lehmann, Frank and Beckert, Rainer and Guenther, Wolfgang and Goerls, Helmar (1999) New indigoid compounds by reduction of bis-imidoylchlorides of oxalic acid - A further evidence for dimeric isocyanides? MONATSHEFTE FUR CHEMIE, 130 (11). pp. 1373-1382. ISSN 0026-9247,

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Abstract

Bis-imidoylchlorides of oxalic acid react rapidly with magnesium shreds in dry THF under ultrasonic conditions to give 1,5-naphthyridine derivatives and the isomeric indigodianiles. Using a cross-over experiment the existence of key intermediates corresponding to dimeric isocyanides could be verified.

Item Type: Article
Uncontrolled Keywords: ONE-POT SYNTHESIS; AMIDINES; TETRAAMINOETHENES; AMINOLYSIS; dimeric isocyanides; indigodianil; 1,5-naphthyridine; spectroscopic properties
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Analytische Chemie, Chemo- und Biosensorik
Depositing User: Dr. Gernot Deinzer
Date Deposited: 13 Dec 2022 09:40
Last Modified: 13 Dec 2022 09:40
URI: https://pred.uni-regensburg.de/id/eprint/48896

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