Photodegradation of some luminescent polymers

Holzer, W. and Penzkofer, Alfons and Pichlmaier, M. and Bradley, D. D. C. and Blau, W. J. (1999) Photodegradation of some luminescent polymers. CHEMICAL PHYSICS, 248 (2-3). pp. 273-284. ISSN 0301-0104,

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Abstract

The photodegradation of four para-phenylenevinylene and two para-phenylene-ethynylene polymers is investigated in neat films and blended polystyrene films. The monomeric photodegradation yield, phi(D,m), due to cw light excitation at some excitation wavelengths is determined by transmission measurement and numerical data analysis. The temporal developments of the optical density spectra indicate inhomogeneous absorption changes. The monomeric photodegradation yield is of the order of phi(D,m), approximate to 10(-3) to 10(-4) for the investigated para-phenylene-vinylene polymers and of the order of phi(D,m), approximate to 10(-5) to 10(-6) for the studied para-phenylene-ethynylene polymers. (C) 1999 Elsevier Science B.V. All rights reserved.

Item Type: Article
Uncontrolled Keywords: STATE DYE-LASERS; CONJUGATED-POLYMER; SEMICONDUCTING POLYMER; THIN-FILMS; CONDUCTING POLYMER; RHODAMINE 6G; EMISSION; COPOLYMER; MATRICES; SILICA; photodegradation; luminescent polymers; thin films
Subjects: 500 Science > 530 Physics
Divisions: Physics > Institute of Experimental and Applied Physics > Alumni or Retired Professors > Group Alfons Penzkofer
Depositing User: Dr. Gernot Deinzer
Date Deposited: 20 Dec 2022 09:34
Last Modified: 20 Dec 2022 09:34
URI: https://pred.uni-regensburg.de/id/eprint/48940

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