3,4-diazanorcaradienes and 4,5-dihydropyridazines as precursors for new stable azomethine ylides

Boehm, Thomas and Elender, Kurt and Riebel, Peter and Troll, Theodor and Weber, Andreas and Sauer, Juergen (1999) 3,4-diazanorcaradienes and 4,5-dihydropyridazines as precursors for new stable azomethine ylides. TETRAHEDRON, 55 (31). pp. 9515-9534. ISSN 0040-4020,

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Abstract

The synthesis of a new class of stable coloured azomethine ylides 3 derived from 3,4-diazanorcaradienes is reported, which under acid catalysis are transformed to again coloured stable azomethine ylides 4 containing a five-membered 1-aza-1,3-cyclopentadiene skeleton. Azomethine ylides 3 in boiling methanol rearrange to 3,5-diazahomotropilidenes 8 in good yields. (C) 1999 Elsevier Science Ltd. All rights reserved.

Item Type: Article
Uncontrolled Keywords: ; azomethine ylides; diazahomotropilidenes; rearrangement; ring transformation
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie
Depositing User: Dr. Gernot Deinzer
Date Deposited: 24 Jan 2023 13:58
Last Modified: 24 Jan 2023 13:58
URI: https://pred.uni-regensburg.de/id/eprint/49118

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