Ohga, Yasushi and Asano, Tsutomu and Karger, Norbert and Gross, Thomas and Lüdemann, Hans-Dietrich (1999) Dynamic solvent effects in the degenerate isomerization of a hexafluoroacetone anil studied by high-pressure F-19 NMR. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES, 54 (6-7). pp. 417-421. ISSN 0932-0784
Full text not available from this repository.Abstract
The rate of the degenerate isomerization of N-hexafluoroisopropylidene-N',N'-dimethyl-p-phenylenediamine was measured by high-pressure F-19 NMR spectroscopy in a viscous hydrocarbon, 2,4-dicyclohexyl-2-methylpentane. Pressure-induced retardations that cannot be rationalized within the framework of the transition state theory (TST) were observed, and it was concluded that the reaction was cast into the TST-invalid nonequilibrium conditions by high pressure.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | THERMAL Z/E ISOMERIZATION; NUCLEAR-MAGNETIC-RESONANCE; N-BENZYLIDENEANILINES; REACTION VOLUMES; CONFORMATIONAL ISOMERIZATION; FLUCTUATIONS; ACTIVATION; AZOBENZENES; CYCLOHEXANE; MECHANISM; high-pressure F-19 NMR; high-pressure kinetics; hexafluoroacetone anil; degenerate isomerization; dynamic solvent effect |
| Subjects: | 500 Science > 570 Life sciences |
| Divisions: | Biology, Preclinical Medicine > Institut für Biophysik und physikalische Biochemie |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 10 Feb 2023 09:21 |
| Last Modified: | 10 Feb 2023 09:21 |
| URI: | https://pred.uni-regensburg.de/id/eprint/49235 |
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