Brunner, Henri and Krumey, Christian (1999) Enantioselective catalysis - Part 124. Enantioselective Michael reaction catalyzed by optically active transition metal complexes. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 142 (1). pp. 7-15. ISSN 1381-1169
Full text not available from this repository.Abstract
The Michael reaction of acrolein 2 with ethyl 2-oxocyclohexanecarboxylate 1 can be catalyzed enantioselectively with a number of optically active transition metal complexes or in situ combinations of transition metal compounds and optically active ligands. The best results up to 47% ee could be obtained with Co(acac)(2) and 1,2-diphenylethylenediamine. (C) 1999 Elsevier Science B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ASYMMETRIC CATALYSIS; ORGANIC-SYNTHESIS; ALPHA-CYANO; LIGANDS; ACID; Michael reaction; enantioselective catalysis; transition metal complexes |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Henri Brunner |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 10 Feb 2023 11:18 |
| Last Modified: | 10 Feb 2023 11:18 |
| URI: | https://pred.uni-regensburg.de/id/eprint/49241 |
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