Bittner, J. and Schmeer, Georg (1999) Investigations on substituent and solvent effects on solvolysis reactions - Part IX. The influence of polar substituents on the imidazole catalyzed hydrolysis of 2,4-dinitrophenyl acetates in water. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1 (10). pp. 2593-2596. ISSN 1463-9076, 1463-9084
Full text not available from this repository.Abstract
The imidazole catalyzed hydrolysis of polar substituted 2,4-dinitrophenyl acetates in water has been investigated at different temperatures. The observed rates correspond to the bimolecular nucleophilic addition of the imidazole at the carboxylic carbon atom followed by a very fast hydrolysis of the N-acetylimidazole in water. The influence of polar substituents in the acid moiety of the ester molecule on the hydrolysis reaction can be described by an electrostatic dipole-dipole interaction in the same way as the neutral hydrolysis of polar substituted ethyl acetates.
| Item Type: | Article |
|---|---|
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Alumni or Retired Professors > Prof. Dr. Georg Schmeer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 10 Feb 2023 11:20 |
| Last Modified: | 10 Feb 2023 11:20 |
| URI: | https://pred.uni-regensburg.de/id/eprint/49243 |
Actions (login required)
 |
View Item |
