Brunner, Henri and Mijolovic, Darijo and Wrackmeyer, Bernd and Nuber, Bernhard (1999) NMR analysis of trinuclear silver(I) complexes with mu(2)-H bridged group VI metallocene hydrides as ligands and X-ray structure analysis of {[(eta(5)-MeC5H4)(2)Mo(mu(2)-H)(2)](2)Ag}PF6. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 579 (1-2). pp. 298-303. ISSN 0022-328X, 1872-8561
Full text not available from this repository. (Request a copy)Abstract
A mixture of the complexes {[Cp2Mo(mu(2)-H)(2)](2)Ag}PF6 (1), {[Cp2W(mu(2)-H)(2)](2)Ag}PF6 (2) and [Cp2Mo(mu(2)-H)(2)Ag(mu(2)-H)(2)WCp2]PF6 (3) was synthesized. H-1- and H-1{Ag-109}-NMR experiments gave detailed information about structure, bonding and exchange behaviour. Further, the methyl substituted complex {[(eta(5)-C5H4Me)(2)Mo(mu(2)-H)(2)](2)Ag}PF6 (4) was synthesized and characterized by X-ray analysis. H-1-, H-1{Ag-109}- and Mo-95-NMR data are reported. (C) 1999 Elsevier Science S.A. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | AG; bridged trinuclear Ag-Mo- and Ag-W-hydride complexes; H-1-NMR; Ag-109-NMR; Mo-95-NMR; single-crystal X-ray structure analysis |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Henri Brunner |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 14 Feb 2023 11:28 |
| Last Modified: | 14 Feb 2023 11:28 |
| URI: | https://pred.uni-regensburg.de/id/eprint/49253 |
Actions (login required)
 |
View Item |
