Brunner, Henri and Breu, J. and Faustmann, P. (1998) Optically active transition metal compounds, 116 - Bond lengths Co-C(CO), Co-N(NO) and angles L-Co-C(CO), L-Co-N(NO) in tetrahedral complexes. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (12). pp. 1871-1876. ISSN 1434-1948,
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The bond lengths Co-C(CO), Co-N(NO) and angles L-Co-C(CO), L-Co-N(NO) in six tetrahedral complexes. determined by X-ray crystallography, were analysed and compared with the calculated compound Co(CO)(2)(NO)PH3. Distinct differences were found which allow a differentiation of the two similar ligands CO and NO. These differences are used to assign CO and NO Ligands in cases where this has not been possible before including a structure in which the two independent molecules in the unit cell are diastereomers. The relationship seems to hold not only for tetrahedral compounds but also for other polyhedral coordination types.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | POLYATOMIC-MOLECULES; LIGANDS; cobalt complexes; carbonyl complexes; nitrosyl complexes |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Henri Brunner |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 21 Feb 2023 06:54 |
| Last Modified: | 21 Feb 2023 06:54 |
| URI: | https://pred.uni-regensburg.de/id/eprint/49283 |
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