1,2,4,5-tetrazine: Synthesis and reactivity in [4+2]cycloadditions

Sauer, Juergen and Heldmann, Dieter K. and Hetzenegger, Josef and Krauthan, Josef and Sichert, Heinz and Schuster, Johann (1998) 1,2,4,5-tetrazine: Synthesis and reactivity in [4+2]cycloadditions. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (12). pp. 2885-2896. ISSN 1434-193X, 1099-0690

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Abstract

Full details on the reactivity of the title compound as 4 pi component in inverse-type Diels-Alder reactions, including kinetic data, are reported. Donor-substituted alkynes, alkenes, donor-substituted and unsubstituted cycloalkenes, ketene acetals and aminals, as well as several cyclic enol ethers were used as dienophiles in these investigations. A. number of 4-mono- and 4,5-disubstituted pyridazines can easily be obtained by this method.

Item Type: Article
Uncontrolled Keywords: DIELS-ALDER REACTIONS; SUBSTITUTED ACETYLENES; ELECTRON; CYCLOADDITION; 1,2-DIAZINE; DIENOPHILES; DERIVATIVES; COMPLEXES; OLEFINS; ANIONS; alkenes; alkynes; cycloadditions; nitrogen heterocycles; tetrazines
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie
Depositing User: Dr. Gernot Deinzer
Date Deposited: 21 Feb 2023 07:20
Last Modified: 21 Feb 2023 07:20
URI: https://pred.uni-regensburg.de/id/eprint/49288

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