Barthel, Josef and Neueder, Roland and Poepke, Herbert and Wittmann, Harald (1998) Osmotic and activity coefficients of nonaqueous electrolyte solutions. 1. Lithium perchlorate in the protic solvents methanol, ethanol, and 2-propanol. JOURNAL OF SOLUTION CHEMISTRY, 27 (12). pp. 1055-1066. ISSN 0095-9782,
Full text not available from this repository. (Request a copy)Abstract
Vapor pressure lowering by the addition of LiClO4 to the protic solvents methanol (0.04-5.1 m), ethanol (0.03-1.5 m), and 2-propanol (0.05-1.5 m) was measured at 25 degrees C with high precision. The experimental data of the corresponding osmotic coefficients are compared to those obtained by the use of Fitter equations and chemical model calculations. Mean activity coefficients are derived from the osmotic coefficients.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | VAPOR-PRESSURE MEASUREMENTS; TETRAALKYLAMMONIUM SALTS; THERMODYNAMICS; ACETONITRILE; osmotic coefficient; activity coefficient; protic solvents; Pitzer equation; chemical model; lithium perchlorate; methanol; ethanol; 2-propanol |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 21 Feb 2023 08:08 |
| Last Modified: | 21 Feb 2023 08:08 |
| URI: | https://pred.uni-regensburg.de/id/eprint/49310 |
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