The new and simple 'LEGO' system: Its application to the synthesis of superbranched oligopyridines

Pabst, Gunther R. and Sauer, Jürgen (1998) The new and simple 'LEGO' system: Its application to the synthesis of superbranched oligopyridines. TETRAHEDRON LETTERS, 39 (48). pp. 8817-8820. ISSN 0040-4039

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Abstract

The condensation of pyridine-2, 4,6-tricarboxtrisamidrazone 1 with 1,2-dicarbonyl compounds 2 - 3 leads to trisubstituted 1,2,4-triazines 4 - 6. These 1,2,4-triazines can be easily transformed to superbranched pyridines 7 - 9 by [4+2] cycloaddition with norborna-2,5-diene followed by [4+2] cycloreversions of nitrogen and cyclopentadiene. This reaction sequence offers a new, simple and general access to superbranched oligopyridines. (C) 1998 Elsevier Science Ltd. All rights reserved.

Item Type: Article
Uncontrolled Keywords: cycloadditions; oligomers; pyridines; triazines
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie
Depositing User: Dr. Gernot Deinzer
Date Deposited: 10 Feb 2023 11:23
Last Modified: 10 Feb 2023 11:23
URI: https://pred.uni-regensburg.de/id/eprint/49334

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